A Synthetic and Mechanistic Investigation of the Chromium Tricarbonyl-Mediated Masamune–Bergman Cyclization. Direct Observation of a Ground-State Tripletp-Benzyne Biradical-Reference-Cited by-同舟云学术

A Synthetic and Mechanistic Investigation of the Chromium Tricarbonyl-Mediated Masamune–Bergman Cyclization. Direct Observation of a Ground-State Tripletp-Benzyne Biradical

Published:2012-07-13 Issue:15 Volume:31 Page:5396-5404
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Ylijoki Kai E. O.¹,Lavy Séverine¹,Fretzen Angelika¹,Kündig E. Peter¹,Berclaz Théo²,Bernardinelli Gérald³,Besnard Céline³

Affiliation:

1. Department of Organic Chemistry, University of Geneva, 30 Quai E. Ansermet, CH-1211 Geneva 4, Switzerland

2. Department of Physical Chemistry, University of Geneva, 30 Quai E. Ansermet, CH-1211 Geneva 4, Switzerland

3. Laboratory of X-ray Crystallography, University of Geneva, 24 Quai E. Ansermet, CH-1211 Geneva 4, Switzerland

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om300427j

Reference67 articles.

1. Concerning the 1,5-didehydro[10]annulene system

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4. 2,3-Di-propyl-1,4-dehydrobenzene

5. Kinetic evidence for the formation of discrete 1,4-dehydrobenzene intermediates. Trapping by inter- and intramolecular hydrogen atom transfer and observation of high-temperature CIDNP

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