Cationic Zirconium Complexes that Contain Mesityl-Substituted Diamido/Donor Ligands. Decomposition via CH Activation and Its Influence on 1-Hexene Polymerization
Author:
Affiliation:
1. Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om010247k
Reference43 articles.
1. Synthesis of Titanium and Zirconium Complexes That Contain the Tridentate Diamido Ligand, [((t-Bu-d6)N-o-C6H4)2O]2- ([NON]2-) and the Living Polymerization of 1-Hexene by Activated [NON]ZrMe2
2. NMR detection of living intermediates prepared from activated [NON]ZrMe2 ([NON]2−=[(t-Bu-d6-N-o-C6H4)2O]2−) and olefins
3. Synthesis of Titanium, Zirconium, and Hafnium Complexes that Contain Diamido Donor Ligands of the Type [(t-BuN-o-C6H4)2O]2- and an Evaluation of Activated Versions for the Polymerization of 1-Hexene
4. Synthesis of group 4 complexes that contain the tridentate diamido ligands [(ArNCH2CH2)2O]2− (Ar = C6H3-Me2-2,6 or C6H3Pri2-2,6)
5. Synthesis of Group 4 Complexes That Contain the Tridentate Diamido/Donor Ligands [(ArylNCH2CH2)2O]2- and Zirconium Complexes That Contain [(ArylNCH2CH2)2S]2- and an Evaluation of Their Activity for the Polymerization of 1-Hexene
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