The Sulfur–Fluorine Gauche Effect in Coinage-Metal Complexes: Augmenting Conformational Equilibria by Complexation-Reference-Cited by-同舟云学术

The Sulfur–Fluorine Gauche Effect in Coinage-Metal Complexes: Augmenting Conformational Equilibria by Complexation

Published:2016-08-25 Issue:17 Volume:35 Page:3040-3044
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Santschi Nico¹²,Thiehoff Christian¹,Holland Mareike C.¹³,Daniliuc Constantin G.¹,Houk K. N.³,Gilmour Ryan¹²

Affiliation:

1. Institute for Organic Chemistry, Westfälische Wilhelms-Universität Münster, Corrensstrasse 40, 48149 Münster, Germany

2. Excellence Cluster EXC 1003, Cells in Motion, Westfälische Wilhelms-Universität Münster, 48149 Münster, Germany

3. Department of Chemistry and Biochemistry, University of California Los Angeles, 607 Charles E. Young Drive East, Los Angeles 90095-1569, United States

Funder

European Research Council

German Academic Exchange Service

Westfälische Wilhelms-Universität Münster

Deutsche Forschungsgemeinschaft

Swiss National Science Foundation

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.6b00564

Reference25 articles.

1. Gauche effect. Stereochemical consequences of adjacent electron pairs and polar bonds

2. Understanding organofluorine chemistry. An introduction to the C–F bond

3. The C–F bond as a conformational tool in organic and biological chemistry

4. Fluorine Conformational Effects in Organocatalysis: An Emerging Strategy for Molecular Design

5. The Fluorine-Iminium IonGaucheEffect: Proof of Principle and Application to Asymmetric Organocatalysis

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