Syntheses, Structural Aspects, Solution Behavior, and Catalytic Utility of Cyclopalladated N,N′,N″-Triarylguanidines [κ2(C,N))Pd(Pyrazole)2X] (X = Br, OC(O)CF3, and PF6) in Suzuki–Miyaura Coupling Reactions of Aryl Bromides
Author:
Affiliation:
1. Department of Chemistry, University of Delhi, Delhi 110 007, India
2. Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bengaluru 560 012, India
Funder
Council of Scientific and Industrial Research
Department of Science and Technology, Ministry of Science and Technology
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.6b00442
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2. Kinetics and mechanism of halogen-bridge cleavage in dimethylaminomethylphenyl-C 1,N pallada- and platina-cycles by pyridines. pressure effects, and crystal structures of the N,N-cis reaction product, its N,N-trans orthometallated analogue and a dimer of similar reactivity
3. The first NH aldimine organometallic compound. Isolation and crystal structureElectronic supplementary information (ESI) available: experimental section. See http://www.rsc.org/suppdata/cc/b2/b211808d/
4. Deamination of the Amino Acid Fragment in Imine Metallacycles: Unexpected Synthesis of an NH-Aldimine Organometallic Compound
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