The Strange Case of Sodium (S)-N-α-(Methylbenzyl)allylamide: Anion Rearrangement, Decomposition, and a Peculiar Propyl Addition
Author:
Affiliation:
1. School of Chemistry, Monash University, Clayton, Victoria 3800, Australia
Funder
Monash University
Australian Research Council
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.5b00979
Reference21 articles.
1. Alkali-Metal-Induced C–C Bond Cleavage and CH4 Elimination in the Amido → Aza-Allyl Transformation of the (S)-N-α-(Methylbenzyl)benzylamido Anion
2. Anion Rearrangements of Alkali Metal Complexes of the Chiral Amine (S)-N-α-(Methylbenzyl)phenylallylamine: Structural and Solution Insights
3. A new type of structure in sodium amide ring chemistry: crystal structure of [PhCH2(Me)NNa(tmeda)]2 showing a buckled, rather than the normal planar, (NNa)2 cyclic ring, with a cisoid, rather than the normal transoid, arrangement of amido-substituents (tmeda = tetramethylethylenediamine)
4. Thermodynamically Favored Anion Rearrangements in Li and Na Complexes of (S)-N-α-(Methylbenzyl)allylamine
5. Solid state structures of homo- and hetero-bimetallic alkali metal complexes containing the dianion of (S)-N-(α-methylbenzyl)allylamine
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