Computational and Experimental Study on Selective sp2/sp3 or Vinylic/Aryl Carbon–Hydrogen Bond Activation by Platinum(II): Geometries and Relative Stability of Isomeric Cycloplatinated Compounds-Reference-Cited by-同舟云学术

Computational and Experimental Study on Selective sp2/sp3 or Vinylic/Aryl Carbon–Hydrogen Bond Activation by Platinum(II): Geometries and Relative Stability of Isomeric Cycloplatinated Compounds

Published:2015-06-25 Issue:13 Volume:34 Page:3303-3313
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Li Yumin¹,Carroll Jeffrey¹,Simpkins Bradley¹,Ravindranathan Deepak¹,Boyd Christopher M.¹,Huo Shouquan¹

Affiliation:

1. Department of Chemistry, East Carolina University, Greenville, North Carolina 27858, United States

Funder

American Chemical Society Petroleum Research Fund

Burroughs Wellcome Fund

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.5b00326

Reference50 articles.

1. Solvent-controlled switch of selectivity between sp2and sp3C–H bond activation by platinum(ii)

2. Reaction of N-Isopropyl-N-phenyl-2,2′-bipyridin-6-amine with K2PtCl4: Selective C–H Bond Activation, C–N Bond Cleavage, and Selective Acylation

3. Cyclopalladation of N-mesitylbenzylideneamines. Aromatic versus aliphatic carbon-hydrogen bond activation

4. Reactivity of 6-(2-tolyl)- and 6-(2,6-xylyl)-2,2′-bipyridines with palladium(II) derivatives. Selective C(sp3)H vs. C(sp2)H activation

5. Versatile Behavior of the Schiff Base Ligand 2,5-Me2C6H3C(H)═N(2,4,6-Me3C6H2) toward Cyclometalation Reactions: C(sp2,phenyl)−H vs C(sp3,methyl)−H Activation

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