Formation of a μ3-Acetylide on a Ru3 Cluster via Coupling of μ-Methylene with Isocyanide Accompanied by Elimination of Amine: A Model of Hydrogen-Assisted C–C Bond Formation on a Metal Surface
Author:
Affiliation:
1. Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8552, Japan
Funder
Core Research for Evolutional Science and Technology
Hiki Foundation, Tokyo Institute of Technology
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
http://pubs.acs.org/doi/pdf/10.1021/acs.organomet.9b00301
Reference42 articles.
1. Organometallic chemistry and surface science: mechanistic models for the Fischer–Tropsch synthesis
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3. Fischer–Tropsch, organometallics, and other friends
4. The lively chemistry of the di-μ-methylene-bis(pentamethylcyclopentadienyl-rhodium) complexes, analogues of surface reactions in heterogeneous catalysis
5. Reactions of diazomethane on transition-metal surfaces and their relationship to the mechanism of the Fischer-Tropsch reaction
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1. Synthesis of a 50-electron triangular ruthenium cluster containing a μ3-methylidyne ligand via the fragmentation of the Ru2 skeleton;Journal of Organometallic Chemistry;2024-06
2. Construction of Two-Faced (Hetero)hydrocarbyl Diiron Complexes Mediated by the Interplay of Ligands;Organometallics;2023-03-29
3. A comparative structural and spectroscopic study of diiron and diruthenium isocyanide and aminocarbyne complexes;Inorganica Chimica Acta;2022-06
4. The Mechanism of the Intramolecular Hydrocarbyl Metathesis within a Planar Triruthenium Cluster: Combining Core Flexibility with Hydride Mobility;Chemistry – A European Journal;2020-09-28
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