Migratory Insertion into a Hafnium–Phenyl Bond and a Ligand-Assisted Mechanism for Reversible Chain Transfer in the Living Coordinative Polymerization of Olefins
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland20742, United States,
2. Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware19716, United States
Funder
Division of Chemistry
National Institute of Standards and Technology
National Institutes of Health
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.2c00364
Reference49 articles.
1. Ex Uno Plures (“Out of One, Many”): New Paradigms for Expanding the Range of Polyolefins through Reversible Group Transfers
2. Frontiers in Olefin Polymerization: Reinventing the World’s Most Common Synthetic Polymers
3. From Multisite Polymerization Catalysis to Sustainable Materials and All-Polyolefin Composites
4. Improving the strength of polyethylene solids by simple controlling of the molecular weight distribution
5. Tunable modalities in polyolefin synthesis via coordination insertion catalysis
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