Experimental and DFT Study of the [AuAr(AsPh3)]-Catalyzed cis/trans Isomerization of [PdAr2(AsPh3)2] (Ar = C6F5 or C6Cl2F3): Alternative Mechanisms and Its Switch upon Pt for Pd Substitution-Reference-Cited by-同舟云学术

Experimental and DFT Study of the [AuAr(AsPh3)]-Catalyzed cis/trans Isomerization of [PdAr2(AsPh3)2] (Ar = C6F5 or C6Cl2F3): Alternative Mechanisms and Its Switch upon Pt for Pd Substitution

Published:2020-06-10 Issue:12 Volume:39 Page:2295-2303
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Villar Pedro¹^ORCID,Pérez-Temprano Mónica H.²^ORCID,Casares Juan A.²^ORCID,Álvarez Rosana¹^ORCID,Espinet Pablo²^ORCID

Affiliation:

1. Departamento de Química Orgánica, Facultade de Química, CINBIO and IIS Galicia Sur, Universidade de Vigo, E-36310, Vigo, Spain

2. IU CINQUIMA/Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, 47071, Valladolid, Spain

Funder

European Regional Development Fund

Ministerio de Econom?a y Competitividad

Xunta de Galicia

Junta de Castilla y Le?n

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.0c00245

Reference53 articles.

1. A Novel Reversible Aryl Exchange Involving Two Organometallics: Mechanism of the Gold(I)-Catalyzed Isomerization of trans-[PdR2L2] Complexes (R = Aryl, L = SC4H8)

2. Silver- and gold-containing heterobinuclear hydrido-bridged complexes

3. Neutral and anionic binuclear perhalogenophenyl platinum–silver complexes with Pt→Ag bonds unsupported by covalent bridges. Molecular structures of [(tht)(C6Cl5)(C6F5)2-PtAg(PPh3)], [NBu4][(C6F5)4PtAg(tht)] and [NBu4][cis-(C6Cl5)2(C6F5)2PtAg(tht)](tht = tetrahydrothiophene)

4. Bimetallic Catalysis using Transition and Group 11 Metals: An Emerging Tool for CC Coupling and Other Reactions

5. Bimetallic catalysis for C–C and C–X coupling reactions

Cited by 6 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Anionic N-Heterocyclic Carbene Gold(I) Complexes from Sydnones as a Precarbenic Unit: A Comprehensive Study of the Au–C sp² Bond Stability Compared to Its “Relative” Imidazole;Organometallics;2023-12-28

2. Dynamic Au–C σ-Bonds Leading to an Efficient Synthesis of [n]Cycloparaphenylenes (n = 9–15) by Self-Assembly;JACS Au;2022-07-11

3. Heteropolymetallic Architectures as Snapshots of Transmetallation Processes at Different Degrees of Transfer;Chemistry – A European Journal;2022-01-19

4. Janus-type homo-, hetero- and mixed valence-bimetallic complexes with one metal encapsulated in a cyclodextrin;Chemical Communications;2022

5. Cyclic Diplatinum Complex with a Tröger's Base Ligand and Reductive Elimination of a Highly Strained Ring Molecule;Zeitschrift für anorganische und allgemeine Chemie;2021-06-08