Steps Ahead in Understanding the Catalytic Isomerization Mechanism of Linear Allylic Alcohols in Water: Dynamics, Bonding Analysis, and Crystal Structure of an η2-Allyl-Intermediate-Reference-Cited by-同舟云学术

Steps Ahead in Understanding the Catalytic Isomerization Mechanism of Linear Allylic Alcohols in Water: Dynamics, Bonding Analysis, and Crystal Structure of an η2-Allyl-Intermediate

Published:2020-12-08 Issue:24 Volume:39 Page:4491-4499
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Scalambra Franco¹,Lopez-Sanchez Belen¹,Holzmann Nicole²³^ORCID,Bernasconi Leonardo⁴^ORCID,Romerosa Antonio¹^ORCID

Affiliation:

1. Área de Química Inorgánica-CIESOL, Universidad de Almería, Almería 04120, Spain

2. Research Center for Computer-Aided Drug Discovery, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China

3. Scientific Computing Department, STFC Rutherford Appleton Laboratory, Harwell Oxford, Didcot OX11 0QX, United Kingdom

4. Center for Research Computing, University of Pittsburgh, 4420 Bayard Street, Pittsburgh, Pennsylvania 15260, United States

Funder

Consejer?a de Econom?a, Innovaci?n, Ciencia y Empleo, Junta de Andaluc?a

Secretar?a de Estado de Investigaci?n, Desarrollo e Innovaci?n

University of Pittsburgh Center for Research Computing

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.0c00585

Reference25 articles.

1. Homogeneously catalysed isomerisation of allylic alcohols to carbonyl compounds

2. Transposition of Allylic Alcohols into Carbonyl Compounds Mediated by Transition Metal Complexes

3. Ruthenium-Catalyzed Isomerizations of Allylic and Propargylic Alcohols in Aqueous and Organic Media: Applications in Synthesis

4. Allylic alcohols as synthetic enolate equivalents: Isomerisation and tandem reactions catalysed by transition metal complexes

5. Catalysis of redox isomerization of allylic alcohols by [RuClCp(mPTA)2](OSO2CF3)2 and [RuCp(mPTA)2(OH2-κO)](OSO2CF3)3·(H2O)(C4H10O)0.5. Unusual influence of the pH and interaction of phosphate with catalyst on the reaction rate

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