Cationic Phosphorus Compounds Based on a Bis(1-piperidinyl)-Substituted Carbodiphosphorane: Syntheses, Structures, and Csp3–H Activation
Author:
Affiliation:
1. Chair of Inorganic Chemistry II, Faculty of Chemistry and Biochemistry, Ruhr-University Bochum, Universitätsstraße 150, 44801 Bochum, Germany
Funder
H2020 European Research Council
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
http://pubs.acs.org/doi/pdf/10.1021/acs.organomet.0c00412
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1. Main-group elements as transition metals
2. 25 years of N-heterocyclic carbenes: activation of both main-group element–element bonds and NHCs themselves
3. Analogous .alpha.,.alpha.'-bis-carbenoid, triply bonded species: synthesis of a stable .lambda.3-phosphino carbene-.lambda.5-phosphaacetylene
4. A stable crystalline carbene
5. Stable Carbenes
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