Synthesis of an Electron-Deficient Triruthenium Hydrido Complex Having a Bridging Carbonyl Ligand: Influence of a CO Ligand on the Properties and Reactivities of a Hydrido Cluster
Author:
Affiliation:
1. Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8552, Japan
2. JST, ACT-C, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan
Funder
Japan Science and Technology Agency
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.7b00465
Reference98 articles.
1. Activation of Linear Alkanes by a Hydrido Triruthenium Cluster and Associated Skeletal Rearrangements
2. Synthesis, Structures, and Reactions of Coordinatively Unsaturated Trinuclear Ruthenium Polyhydrido Complexes, [{Ru(C5Me5)}3(μ-H)6](Y) (Y = BF4, CF3SO3, 1/2(SO4), C6H5CO2, CH3CO2, B(C6H5)4, PF6) and [{Ru(C5Me5)}3(μ-H)3(μ3-H)2]
3. Activation of Organic Substrates on Multi-Metallic Sites of Transition Metal Polyhydride Clusters Having C5Me5 Groups as Auxiliary Ligands
4. Intermolecular Activation ofn-Alkanes by a Trinuclear Ruthenium Pentahydride Complex—Formation ofcloso-Ruthenacyclopentadiene Complexes
5. Alkane activation on a multimetallic site
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