Mechanistic Insights into Scandium-Catalyzed Hydroaminoalkylation of Olefins with Amines: Origin of Regioselectivity and Charge-Based Prediction Model-Reference-Cited by-同舟云学术

Mechanistic Insights into Scandium-Catalyzed Hydroaminoalkylation of Olefins with Amines: Origin of Regioselectivity and Charge-Based Prediction Model

Published:2017-04-10 Issue:8 Volume:36 Page:1557-1565
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Liu Fan¹,Luo Gen¹²,Hou Zhaomin¹²^ORCID,Luo Yi¹^ORCID

Affiliation:

1. State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, People’s Republic of China

2. Organometallic Chemistry Laboratory and RIKEN Center for Sustainable Resource Science, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan

Funder

Japan Society for the Promotion of Science

National Natural Science Foundation of China

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

http://pubs.acs.org/doi/pdf/10.1021/acs.organomet.7b00116

Reference74 articles.

1. Synthesis of secondary amines

2. Direct sp3C–H bond activation adjacent to nitrogen in heterocycles

3. Catalytic C−H Activation of sp3 C−H Bonds inα-Position to a Nitrogen Atom—Two New Approaches

4. CatalyticC-Alkylation of Secondary Amines with Alkenes

5. Catalytic C-H activation in early transition-metal dialkylamides and alkoxides

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