Theoretical Insight into C(sp3)–F Bond Activations and Origins of Chemo- and Regioselectivities of “Tunable” Nickel-Mediated/-Catalyzed Couplings of 2-Trifluoromethyl-1-alkenes with Alkynes-Reference-Cited by-同舟云学术

Theoretical Insight into C(sp3)–F Bond Activations and Origins of Chemo- and Regioselectivities of “Tunable” Nickel-Mediated/-Catalyzed Couplings of 2-Trifluoromethyl-1-alkenes with Alkynes

Published:2017-09-28 Issue:19 Volume:36 Page:3739-3749
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Zhang Xiaomin¹,Liu Yuxia¹^ORCID,Chen Guang¹,Pei Guojing¹,Bi Siwei¹^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, People’s Republic of China

Funder

National Natural Science Foundation of China

Shandong Provincial Key Laboratory of Detection Technology for Tumor Markers

Scientific Research Foundation, Qufu Normal University

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.7b00514

Reference67 articles.

1. C−F Bond Activation in Organic Synthesis

2. C−F and C−H Bond Activation of Fluorobenzenes and Fluoropyridines at Transition Metal Centers: How Fluorine Tips the Scales

3. Synthesis of Fluorinated Building Blocks by Transition-Metal-Mediated Hydrodefluorination Reactions

4. The Bridged Binding Mode as a New, Versatile Template for the Selective Activation of Carbon−Fluorine Bonds in Fluoroolefins: Activation of Trifluoroethylene

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