Olefin Insertion Versus Cross-Coupling in trans-[Pd(Ar)X(AsPh3)2] Complexes (X = I, F, CF3) Treated with a Phosphine-EWOlefin Ligand to Induce Ar

Olefin Insertion Versus Cross-Coupling in trans-[Pd(Ar)X(AsPh3)2] Complexes (X = I, F, CF3) Treated with a Phosphine-EWOlefin Ligand to Induce Ar–X Coupling

Published:2017-07-13 Issue:15 Volume:36 Page:2884-2890
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

del Pozo Juan¹^ORCID,Gioria Estefanía¹^ORCID,Espinet Pablo¹^ORCID

Affiliation:

1. IU CINQUIMA/Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, 47071 Valladolid, Spain

Funder

Ministerio de Econom?a y Competitividad

Fundaci?n Alfonso Mart?n Escudero

Ministerio de Educaci?n, Cultura y Deporte

Junta de Castilla y Le?n

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

http://pubs.acs.org/doi/pdf/10.1021/acs.organomet.7b00353

Reference81 articles.

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3. Facile Ar−CF3 Bond Formation at Pd. Strikingly Different Outcomes of Reductive Elimination from [(Ph3P)2Pd(CF3)Ph] and [(Xantphos)Pd(CF3)Ph]

4. CF3–Ph Reductive Elimination from [(Xantphos)Pd(CF3)(Ph)]

5. The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides

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