Tris(pentamethylcyclopentadienyl) Complexes of Late Lanthanides Tb, Dy, Ho, and Er: Solution and Mechanochemical Syntheses and Structural Comparisons
Author:
Affiliation:
1. Department of Chemistry, University of California, Irvine, California 92697-2025, United States
Funder
Division of Chemistry
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
http://pubs.acs.org/doi/pdf/10.1021/acs.organomet.7b00385
Reference34 articles.
1. Pentamethylcyclopentadienyl derivatives of the trivalent lanthanide elements neodymium, samarium, and ytterbium
2. Mono-η-cycloheptatrienyltitanium chemistry: synthesis, molecular and electronic structures, and reactivity of the complexes [Ti(η-C7H7)L2X](L = tertiary phosphine, O- or N-donor ligand; X = Cl or alkyl)
3. Synthesis and x-ray crystal structure of the first tris(pentamethylcyclopentadienyl)metal complex: (.eta.5-C5Me5)3Sm
4. Reactivity of (C5Me5)2Sm with cyclopentadiene and cyclopentadienide: isolation of the mixed-valence complex (C5Me5)2Sm(III)(.mu.-C5H5)Sm(II)(C5Me5)2
5. The expansion of divalent organolanthanide reduction chemistry via new molecular divalent complexes and sterically induced reduction reactivity of trivalent complexes
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