Rapid and Mild Synthesis of an NHC-Coordinated Bis(trimethylsilyl)silylene via Elimination of Halotrimethylsilane
Author:
Affiliation:
1. Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
Funder
Japan Society for the Promotion of Science
Mitsubishi Foundation
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.1c00380
Reference59 articles.
1. Silylenes
2. Stable Heavier Carbene Analogues
3. N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands
4. Stable Silylenes and Their Transition Metal Complexes
5. Decamethylsilicocene-Synthesis and Structure
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1. Silacyclopropenylsilylene-NHC Complex: Synthesis by (1+2) Retro-cycloaddition, Dynamic Behavior in Solution, and Ring-expansion Reaction;Chemistry Letters;2023-02-05
2. The Insertion of E II and E IV Chlorides (E=Si, Ge) into the Si−Si Bond of Disilylene;Chemistry – A European Journal;2022-11-22
3. An NHC‐Mediated Metal‐Free Approach towards an NHC‐Coordinated Endocyclic Disilene;ChemistryOpen;2022-02-09
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