Toluene and α-Olefins as Radical Scavengers: Direct NMR Evidence for Homolytic Chain Transfer Mechanism Leading to Benzyl and “Dormant” Titanium Allyl Complexes
Author:
Affiliation:
1. Dipartimento di Scienze Chimiche, Università di Napoli Federico II, Via Cintia, 80126 Napoli, Italy
2. Dipartimento di Chimica, Biologia e Biotecnologie and CIRCC, Università di Perugia, Via Elce di Sotto 8, 06123 Perugia, Italy
Funder
University of Perugia and MUIR
MUIR Progetti di Rilevante Interesse Nazionale (PRIN)
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
http://pubs.acs.org/doi/pdf/10.1021/acs.organomet.8b00755
Reference50 articles.
1. Deactivation in Homogeneous Transition Metal Catalysis: Causes, Avoidance, and Cure
2. Zirconocene-Catalyzed Propene Polymerization: A Quenched-Flow Kinetic Study
3. Reactivity of Secondary Metallocene Alkyls and the Question of Dormant Sites in Catalytic Alkene Polymerization
4. "Dormant" secondary metal-alkyl complexes are not omnipresent
5. Reactivity of Secondary Metal−Alkyls in Catalytic Propene Polymerization: How Dormant Are “Dormant Chains”?
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