Axially Chiral, Electrophilic Fluorophosphonium Cations: Synthesis, Lewis Acidity, and Reactivity in the Hydrosilylation of Ketones
Author:
Affiliation:
1. Institut für Chemie, Technische Universität Berlin, Strasse des 17. Juni 115, 10623 Berlin, Germany
2. Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6
Funder
Canada Research Chairs
Einstein Stiftung Berlin
Natural Sciences and Engineering Research Council of Canada
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.8b00912
Reference58 articles.
1. Lewis Acidity of Organofluorophosphonium Salts: Hydrodefluorination by a Saturated Acceptor
2. A Tale of Two Elements: The Lewis Acidity/Basicity Umpolung of Boron and Phosphorus
3. Phosphorus Lewis acids: emerging reactivity and applications in catalysis
4. Metal-free transfer hydrogenation of olefins via dehydrocoupling catalysis
5. Catalytic Ketone Hydrodeoxygenation Mediated by Highly Electrophilic Phosphonium Cations
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