Redox-Rich Metallocene Tetrazene Complexes: Synthesis, Structure, Electrochemistry, and Catalysis

Author:

Vanicek Stefan1,Jochriem Markus1,Hassenrück Christopher2,Roy Souvik3ORCID,Kopacka Holger1,Wurst Klaus1,Müller Thomas4,Winter Rainer F.2ORCID,Reisner Erwin3,Bildstein Benno1ORCID

Affiliation:

1. Institute of General, Inorganic and Theoretical Chemistry, Center for Chemistry and Biomedicine, University of Innsbruck, Innrain 80-82, A-6020 Innsbruck, Austria

2. Department of Chemistry, University of Konstanz, Universitätsstrasse 10, D-78457 Konstanz, Germany

3. Christian Doppler Laboratory for Sustainable SynGas Chemistry, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, U.K.

4. Institute of Organic Chemistry, Center for Chemistry and Biomedicine, University of Innsbruck, Innrain 80-82, A-6020 Innsbruck, Austria

Funder

Austrian Science Fund

Deutsche Forschungsgemeinschaft

H2020 Marie Sklodowska-Curie Actions

Christian Doppler Forschungsgesellschaft

OMV Aktiengesellschaft

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference46 articles.

1. Review: Comprehensive Coordination Chemistry, The Synthesis, Reactions, Properties & Applications of Coordination Compounds; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds. Pergamon Press: Oxford, U.K., 1987; Vol. 2, Chapter 13.5, pp 217–224.

2. Organic azides and isocyanates as sources of nitrene species in organometallic chemistry

3. .pi.-Cyclopentadienyl(1,4-tetraazendiyl)cobalt

4. Conversion of aryl azides on nickel centers into tetraazadiene-nickel complexes [Ni0(Ar2N4)2], [CpNiI(Ar2N4)], and [(RNC)2Ni0(Ar2N4)]. Crystal structure of [Ni0{1,4-(3,5-Me2C6H3)2N4}2]

5. Delocalized .pi. bonding in tetraazadiene metallocycles

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