Origin of Product Selectivity in Yttrium-Catalyzed Benzylic C–H Alkylations of Alkylpyridines with Olefins: A DFT Study-Reference-Cited by-同舟云学术

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Origin of Product Selectivity in Yttrium-Catalyzed Benzylic C–H Alkylations of Alkylpyridines with Olefins: A DFT Study

Published:2018-08-03 Issue:16 Volume:37 Page:2741-2748
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Zhou Guangli¹,Luo Gen¹^ORCID,Kang Xiaohui²,Hou Zhaomin¹³^ORCID,Luo Yi¹^ORCID

Affiliation:

1. State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, People’s Republic of China

2. College of Pharmacy, Dalian Medical University, Dalian, Liaoning 116044, People’s Republic of China

3. Organometallic Chemistry Laboratory and RIKEN Center for Sustainable Resource Science, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan

Funder

Ministry of Education of the People's Republic of China

National Natural Science Foundation of China

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.8b00397

Reference59 articles.

1. Zirconium-catalyzed coupling of propene and .alpha.-picoline

2. Synthesis and insertion chemistry of cationic zirconium(IV) pyridyl complexes. Productive .sigma.-bond metathesis

3. Alkene and alkyne insertion reactions of cationic Cp2Zr(.eta.2-pyridyl)(L)+ complexes. Zirconium-mediated functionalization of pyridines

4. Stereoselective Olefin Insertion Reactions of Chiral (EBI)Zr(.eta.2-pyrid-2-yl)+ and (EBTHI)Zr(.eta.2-pyrid-2-yl)+ Complexes

5. Direct functionalization of unactivated C–H bonds catalyzed by group 3–5 metal alkyl complexes

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1. C-H alkylation of pyridines with olefins catalyzed by imidazolin-2-iminato-ligated rare-earth alkyl complexes;Science China Chemistry;2023-05-10

2. Mechanism and Origin of CuH‐Catalyzed Regio‐ and Enantioselective Hydrocarboxylation of Allenes;European Journal of Organic Chemistry;2023-02-15

3. Recent Advances in Rare‐Earth Metal‐Catalyzed C−H Functionalization Reactions;ChemCatChem;2022-11-07

4. Substrate Facilitating Roles in Rare-Earth-Catalyzed C–H Alkenylation of Pyridines with Allenes: Mechanism and Origins of Regio- and Stereoselectivity;Inorganic Chemistry;2022-10-19

5. Yttrium‐Catalyzed ortho ‐Selective C−H Borylation of Pyridines with Pinacolborane;Angewandte Chemie;2022-03-23

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