Divergent Reactivity of CO2, CO, and Related Substrates at the Nickel Carbon Double Bond of (PCcarbeneP)Ni(II) Pincer Complexes
Author:
Affiliation:
1. Department of Chemistry, University of Calgary, 2500 University Drive N.W., Calgary, Alberta, Canada T2N 1N4
Funder
Canada Research Chairs
Natural Sciences and Engineering Research Council of Canada
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.8b00440
Reference54 articles.
1. Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation
2. Structure, Function, and Mechanism of the Nickel Metalloenzymes, CO Dehydrogenase, and Acetyl-CoA Synthase
3. The elusive abnormal CO2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion
4. Direct CO2 Addition to a Ni(0)–CO Species Allows the Selective Generation of a Nickel(II) Carboxylate with Expulsion of CO
5. Formation of a nickel carbon dioxide adduct and its transformation mediated by a Lewis acid
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