Mechanistic Study of Direct Arylation of Indole Using Differential Selectivity Measurements: Shedding Light on the Active Species and Revealing the Key Role of Electrophilic Substitution in the Catalytic Cycle-Reference-Cited by-同舟云学术

Mechanistic Study of Direct Arylation of Indole Using Differential Selectivity Measurements: Shedding Light on the Active Species and Revealing the Key Role of Electrophilic Substitution in the Catalytic Cycle

Published:2018-06-25 Issue:13 Volume:37 Page:2054-2063
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Kurokhtina Anna A.¹,Larina Elizaveta V.¹,Yarosh Elena V.¹,Lagoda Nadezhda A.¹,Schmidt Alexander F.¹^ORCID

Affiliation:

1. Department of Chemistry, Irkutsk State University, K. Marx Str., 1, 664003 Irkutsk, Russia

Funder

Russian Foundation for Basic Research

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.8b00216

Reference26 articles.

1. Direct (Hetero)arylation Reactions of (Hetero)arenes as Tools for the Step- and Atom-Economical Synthesis of Biologically Active Unnatural Compounds Including Pharmaceutical Targets

2. Regioselectivity in palladium-catalysed direct arylation of 5-membered ring heteroaromatics

3. Direct Palladium-Catalyzed C-2 and C-3 Arylation of Indoles: A Mechanistic Rationale for Regioselectivity

4. Palladium-Catalyzed Intermolecular Alkenylation of Indoles by Solvent-Controlled Regioselective CH Functionalization

5. Mechanistic Analysis of Azine N-Oxide Direct Arylation: Evidence for a Critical Role of Acetate in the Pd(OAc)2 Precatalyst

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