Application of a New Chiral Phosphepine to the Catalytic Asymmetric Synthesis of Highly Functionalized Cyclopentenes That Bear an Array of Heteroatom-Substituted Quaternary Stereocenters
Author:
Affiliation:
1. Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja2049012
Reference52 articles.
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3. For reviews of asymmetric catalysis by chiral phosphines, see:Marinetti, A.; Voituriez, A.Synlett 2010, 174–194.Gröger, H.; Burda, E.InPhosphorus Ligands in Asymmetric Catalysis;Börner, A., Ed.Wiley–VCH:New York, 2008; Vol.3, pp1175–1197.
4. Enantioselective catalysis and complexity generation from allenoates
5. Phosphine-Catalyzed Cycloaddition of 2,3-Butadienoates or 2-Butynoates with Electron-Deficient Olefins. A Novel [3 + 2] Annulation Approach to Cyclopentenes
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