How to Build a Metalloenzyme: Lessons from a Protein-Based Model of Acetyl Coenzyme A Synthase
Author:
Affiliation:
1. Departments of Molecular Biosciences and Chemistry, Northwestern University, Evanston, Illinois 60208, United States
Funder
U.S. Department of Energy
Alfred P. Sloan Foundation
Life Sciences Research Foundation
Publisher
American Chemical Society (ACS)
Subject
General Medicine,General Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.accounts.2c00824
Reference59 articles.
1. Multielectron Chemistry within a Model Nickel Metalloprotein: Mechanistic Implications for Acetyl-CoA Synthase
2. A Biochemical Nickel(I) State Supports Nucleophilic Alkyl Addition: A Roadmap for Methyl Reactivity in Acetyl Coenzyme A Synthase
3. Ligand Field Inversion as a Mechanism to Gate Bioorganometallic Reactivity: Investigating a Biochemical Model of Acetyl CoA Synthase Using Spectroscopy and Computation
4. Thioester synthesis by a designed nickel enzyme models prebiotic energy conversion
5. Hydrogenases
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