Tuning Reactivity and Selectivity in Hydrogen Atom Transfer from Aliphatic C–H Bonds to Alkoxyl Radicals: Role of Structural and Medium Effects
Author:
Affiliation:
1. Dipartimento di Scienze e Tecnologie Chimiche, Università “Tor Vergata”, Via della Ricerca Scientifica, 1, I-00133 Rome, Italy
Funder
Ministero dell'Istruzione, dell'Università e della Ricerca
Publisher
American Chemical Society (ACS)
Subject
General Medicine,General Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.accounts.5b00348
Reference50 articles.
1. Understanding Hydrogen Atom Transfer: From Bond Strengths to Marcus Theory
2. Do spin state and spin density affect hydrogen atom transfer reactivity?
3. Hydrogen-Abstraction Reactivity Patterns from A to Y: The Valence Bond Way
4. Thermal Hydrogen-Atom Transfer from Methane: The Role of Radicals and Spin States in Oxo-Cluster Chemistry
5. Polarity-reversal catalysis of hydrogen-atom abstraction reactions: concepts and applications in organic chemistry
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