Computational View of the Mechanism of Vinylphosphirane Pyrolysis and a New Route to Phosphaalkynes
Author:
Affiliation:
1. Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om960696y
Reference40 articles.
1. Synthesis of phosphapropyne by flash thermolysis of 1-vinylphosphirane or divinylphosphine
2. Molecular orbital study of the vinylphosphinidene to phosphapropyne rearrangement
3. The C3H4 surface
4. The kinetics of pyrolysis of 1,3,3-trimethylcyclopropene. Evidence for the involvement of alkylidene carbenes in the thermal isomerisation of cyclopropenes
5. The 1,2 hydrogen shift as an accompaniment to ring closure and opening: ab initio MO study of thermal rearrangements on the C2H3N potential energy hypersurface
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