An Unexpected Highly Stereoselective Bisaziridination of (E,E)-1,4-Dialkyl-2,3-dinitrobutadienes Followed by a Nitro Group Driven Ring Enlargement

Author:

Ciogli Alessia1,Fioravanti Stefania2,Gasparrini Francesco1,Pellacani Lucio2,Rizzato Egon3,Spinelli Domenico3,Tardella Paolo A.2

Affiliation:

1. Dipartimento di Chimica e Tecnologie del Farmaco

2. Dipartimento di Chimica

3. Dipartimento di Chimica “G. Ciamician”, Università degli Studi, Via Selmi 2, I-40126 Bologna, Italy

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Reference50 articles.

1. aSpinelli, D.; Consiglio, G.; Dell’Erba, C.; Novi, M.InThe Chemistry of Heterocyclic Compounds, Thiophene and Its Derivatives;Gronowitz, S., Ed.Wiley:New York, 1991; Vol.44, pp295−396.

2. Nitrobutadienes from ß-nitrothiophenes: valuable building-blocks in the overall ring-opening / ring-closure protocol to homo- or hetero-cycles

3. dTerrier, F.Nucleophilic Aromatic Displacement: The Influence of the Nitro Group;VCH:New York, 1991; pp306−307.

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