Synthesis and Characterization of (Me3ECH2)2Ta(CHEMe3)Si(SiMe3)3 (E = C, Si). Kinetic and Mechanistic Studies of the Formation of a Silyl Alkylidene Complex through Preferential Silane Elimination-Reference-Cited by-同舟云学术

Synthesis and Characterization of (Me3ECH2)2Ta(CHEMe3)Si(SiMe3)3 (E = C, Si). Kinetic and Mechanistic Studies of the Formation of a Silyl Alkylidene Complex through Preferential Silane Elimination

Published:1996-08-06 Issue:16 Volume:15 Page:3520-3527
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Li Liting¹,Diminnie Jonathan B.¹,Liu Xiaozhan¹,Pollitte Jonathan L.¹,Xue Ziling¹

Affiliation:

1. Department of Chemistry, The University of Tennessee, Knoxville, Tennessee 37996-1600

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om960382a

Reference41 articles.

1. Silylhexacarbonylvanadium: a volatile seven-coordinate derivative of vanadium(I)

2. Early-Transition-Metal Silyl Complexes Free from Anionic .pi.-Ligands. A New Family of Alkyl, Alkylidene, and Alkylidyne Compounds

3. Early-Transition-Metal Silyl Complexes Free of Anionic π-Ligands. A Comparison of Alkyl and Silyl Ligands

4. Alkylcarbene complex of tantalum by intramolecular .alpha.-hydrogen abstraction

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