Reduction of Water to H2 by Diorganopalladium(II) Complexes of Tris(pyrazol-1-yl)borate: Ab-Initio Theoretical Study of the Mechanism
Author:
Affiliation:
1. Laboratoire de Chimie Quantique, UPR 139 du CNRS, Université Louis Pasteur, 4, rue Blaise Pascal, F 67000 Strasbourg, France, and Department of Chemistry, University of Tasmania, Hobart, Tasmania, Australia
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om9702338
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4. Oxidation of organoplatinum(II) and -palladium(II) complexes by water. The X-ray structure of the trimethylpalladium(IV) complex fac-[PdMe3{tris(pyrazol-1-yl)borate}] formed on oxidation of a dimethylpalladium(II) reagent
5. Oxidation reactions using water, hydrogen peroxide and halogens to give pallad(IV) cyclopentane complexes PdX(C4H8 {(pz)3BH} (X = OH, Cl, Br, I). The crystal structure of the hydroxoplatinum(IV) complex Pt(OH)Me2{(pz)3BH}, formed by use of water as an oxidant
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