Cooperative Effects of Electron Donors and Acceptors for the Stabilization of Elusive Metal Cluster Frameworks: Synthesis and Solid-State Structures of [Pt19(CO)24(μ4-AuPPh3)3]− and [Pt19(CO)24{μ4-Au2(PPh3)2}2]-Reference-Cited by-同舟云学术

Cooperative Effects of Electron Donors and Acceptors for the Stabilization of Elusive Metal Cluster Frameworks: Synthesis and Solid-State Structures of [Pt19(CO)24(μ4-AuPPh3)3]− and [Pt19(CO)24{μ4-Au2(PPh3)2}2]

Published:2013-01-30 Issue:4 Volume:52 Page:1960-1964
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Ceriotti Alessandro¹,Macchi Piero²,Sironi Annalisa³,El Afefey Simona¹⁴,Daghetta Matteo⁵,Fedi Serena⁴,de Biani Fabrizia Fabrizi⁴,Della Pergola Roberto³

Affiliation:

1. Dipartimento di Chimica, Università degli Studi di Milano, via Golgi 19, 20133 Milano, Italy

2. Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, 3012 Bern, Switzerland

3. Dipartimento di Scienze dell’Ambiente e del Territorio, Università di Milano—Bicocca, piazza della Scienza 1, 20126 Milano, Italy

4. Dipartimento di Chimica, Università degli Studi di Siena, via Aldo Moro, 53100 Siena, Italy

5. Dipartimento di Chimica, Materiali e Ingegneria Chimica “Giulio Natta”, Politecnico di Milano, Piazza L. Da Vinci 32, 20133 Milano, Italy

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic302282y

Reference48 articles.

1. Formation of trinuclear clusters by addition of (triphenylphosphine)gold(1+) to dinuclear platinum(I) complexes containing bridging cyclometalated arylphosphines. X-ray structure of [(Ph3P)AuPt2{C6H4P(Ph)CH2CH2CH2PPh2}2]BF4

2. Synthesis of the First Pt-Au Cluster by an Unexpected H⊕-Substitution attrans-PtH(Cl)L2

3. Gold-197 Mössbauer spectra and the bonding of some gold–gold and gold–platinum clusters

4. Synthesis and structural characterisation of [Pt2Au2(PPh3)4(CNC6H3Me2-2,6)4][PF6]2; a platinum–gold cluster with a distorted butterfly geometry

5. Synthesis and structure of Pt2Au cluster complexes, including [Pt2(C.ident.C-t-Bu)2(.mu.-AuI)(.mu.-Ph2PCH2PPh2)2]

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