An On/Off Circular Dichroism Signal Reveals a pH Dependent Competition between a Cyclodextrin and a Polyelectrolyte for an Atropisomeric Aromatic Guest-Reference-Cited by-同舟云学术

An On/Off Circular Dichroism Signal Reveals a pH Dependent Competition between a Cyclodextrin and a Polyelectrolyte for an Atropisomeric Aromatic Guest

Published:1997-12-17 Issue:50 Volume:119 Page:12404-12405
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Yang Sung Yun¹,Green Mark M.¹,Schultz Gerald¹,Jha Salil K.¹,Müller Axel H. E.¹

Affiliation:

1. Herman F. Mark Polymer Research Institute Polytechnic University, Six Metrotech Center Brooklyn, New York 11201 Institute of Physical Chemistry, University of Mainz Welderweg 15D-55099 Mainz, Germany

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja972789s

Reference16 articles.

1. Symmetry rules for the determination of the intercalation geometry of host/systems using circular dichroism: a symmetry-adapted coupled-oscillator model

2. Study of Photopolymers XXXXII. Synthesis and Photochemical Reaction of Water Soluble Self-Sensitized Photoreactive Polymers Using 1,8-Diazabicyclo-[5.4.0]-7-undecene (DBU) Method

3. The binding constantKfor the complex between the binaphthyl label in1was evaluated from the intensity of the ICD following a published method (Ueno, A.; Moriwaki, F.; Osa, T.; Hamada, F.; Murai, K.J. Am. Chem. Soc.1988,110, 4323) under the following conditions which pertain to all measurements reported in this work: [PMA] = 0.01 M, [K+] = 0.1 M, 20 °C.

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