A Molecular Model To Explain and Predict the Stereoselectivity in Rhodium-Catalyzed Hydroformylation

Author:

Gleich Dieter1,Schmid Rochus1,Herrmann Wolfgang A.1

Affiliation:

1. Anorganisch-chemisches Institut, Technische Universität München, Lichtenbergstrasse 4, D-85747 Garching, Germany, and Department of Chemistry, University of Calgary, 2500 University Drive, Northwest, Calgary, Alberta, Canada T2N 1N4

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference32 articles.

1. Reviews:  (a) Herrmann, W. A.; Cornils, B.Angew. Chem., Int. Ed. Engl.1997,36, 1047. (b) Cornils, B.; Herrmann, W. A. InApplied HomogeneousCatalysis with Organometallic Compounds; VCH−Wiley:  Weinheim, 1996; Vol. 1, pp 3−25. (c) Cornils, B.; Herrmann, W. A.; Rasch, M.Angew. Chem.Int. Ed. Engl.1994,33, 2144.

2. (a) Frohning, C. D.; Kohlpaintner, C. W. InApplied Homogeneous Catalysis withOrganometallic Compounds; VCH−Wiley:  Weinheim, 1996; Vol. 1, pp 29−104.

3. Water-Soluble Ligands, Metal Complexes, and Catalysts: Synergism of Homogeneous and Heterogeneous Catalysis

4. The asymmetric hydroformylation in the synthesis of pharmaceuticals

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