Structure, Bonding, and Paramagnetism in the Manganese(II) Tris-Allyl Anions [Mn{ηx-(C3H3R2)3}]- (R = H, SiMe3; x = 1 or 3):  Insight from Theory

Author:

Layfield Richard A.1,Bühl Michael1,Rawson Jeremy M.1

Affiliation:

1. Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, United Kingdom, and Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr, Germany

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

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1. Cyclic and Non-Cyclic Pi Complexes of Manganese;Reference Module in Chemistry, Molecular Sciences and Chemical Engineering;2021

2. Complexes of Group 7 Metals with Metal-Carbon Sigma and Multiple Bonds;Reference Module in Chemistry, Molecular Sciences and Chemical Engineering;2021

3. Synthesis and Reactivity of Manganese(II) Complexes Containing N-Heterocyclic Carbene Ligands;Organometallics;2015-09-24

4. Manganese: Organometallic Chemistry;Encyclopedia of Inorganic and Bioinorganic Chemistry;2015-06-14

5. Mechanochemical Synthesis of [1,3-(SiMe3)2C3H3]3(Al,Sc), a Base-Free Tris(allyl)aluminum Complex and Its Scandium Analogue;Organometallics;2014-10-08

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