Berberine Cation: A Fluorescent Chemosensor for Alkanes and Other Low-Polarity Compounds. An Explanation of This Phenomenon-Reference-Cited by-同舟云学术

Berberine Cation: A Fluorescent Chemosensor for Alkanes and Other Low-Polarity Compounds. An Explanation of This Phenomenon

Published:2000-06-23 Issue:15 Volume:2 Page:2311-2313
ISSN:1523-7060
Container-title:Organic Letters
language:en
Short-container-title:Org. Lett.

Author:

Cossío Fernando P.¹,Arrieta Ana¹,Cebolla Vicente L.¹,Membrado Luis¹,Vela Jesús¹,Garriga Rosa¹,Domingo María P.¹

Affiliation:

1. Kimika Fakultatea, Euskal Herriko Unibertsitatea, P.K. 1072, 20080 San Sebastián-Donostia, Spain, Instituto de Carboquímica, CSIC, María de Luna, 12, 500015 Zaragoza, Spain, and Grupo de Espectroscopía Analítica y Sensores, Departamento de Química Analítica, Facultad de Veterinaria, Universidad de Zaragoza, 50013 Zaragoza, Spain

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ol006075p

Reference9 articles.

1. Signaling Recognition Events with Fluorescent Sensors and Switches

2. Enhancement of Fluorescence in Thin-Layer Chromatography Induced by the Interaction between n-Alkanes and an Organic Cation

3. Quantitative Applications of Fluorescence and Ultraviolet Scanning Densitometry for Compositional Analysis of Petroleum Products in Thin-Layer Chromatography

4. Procedure details can be found in ref 3a. PM3 semiempirical Hamiltonian at the Hartree−Fock (HF) level was used for a complete geometry optimization of the berberine cation. The ion−molecule complex betweenn-hexane and the berberine cation was optimized at the HF/PM3 level. Finally, geometries of berberine and the berberine−n-hexane complex in the first excited state were optimized at the 3X3CI-HE/PM3 level of theory.

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