Heterolytic Cleavage of a β-Phosphatoxyalkyl Radical Resulting in Phosphate Migration or Radical Cation Formation as a Function of Solvent Polarity
Author:
Affiliation:
1. Department of Chemistry, Wayne State University, Detroit, Michigan 48202, and Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, Illinois 60607-7061
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol990054h
Reference13 articles.
1. Oxidative Strand Scission of Nucleic Acids: Routes Initiated by Hydrogen Abstraction from the Sugar Moiety
2. The .beta.-(phosphonooxy)alkyl radical rearrangement
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