Stereoselective Preparation of Vitamin D Precursors Using the Intramolecular Coupling of Alkynes and Cyclopropylcarbene−Chromium Complexes: A Formal Total Synthesis of (±)-Vitamin D3-Reference-Cited by-同舟云学术

Stereoselective Preparation of Vitamin D Precursors Using the Intramolecular Coupling of Alkynes and Cyclopropylcarbene−Chromium Complexes: A Formal Total Synthesis of (±)-Vitamin D3

Published:1998-03-19 Issue:7 Volume:63 Page:2325-2331
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Yan Jingbo¹,Herndon James W.¹

Affiliation:

1. Department of Chemistry & Biochemistry, New Mexico State University, Box 30001, Department 3C, Las Cruces, New Mexico 88003-8001, and Department of Chemistry & Biochemistry, University of Maryland, College Park, Maryland 20742-2021

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo972186z

Reference20 articles.

1. Synthesis of cyclopentane-fused oxygen heterocycles from the intramolecular reaction of alkynes with cyclopropylcarbene-chromium complexes

2. Effect of solvent polarity extremes on the coupling of cyclopropylcarbene-chromium complexes and alkynes: Synthesis of β-alkoxycyclopentadienones, 2-cyclopentene-1,3-diones, and cis 4,5-disubstituted cyclopentenones

3. Heterocyclic synthesis involving acetylenedicarboxylate adducts of thiosalicylic acid derivatives

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