Transient Palladadiphosphanylcarbenes: Singlet Carbenes with an “Inverse” Electronic Configuration (pπ2 instead of σ2) and Unusual Transannular Metal−Carbene Interactions (πC→Pd Donation and σPd→C Back-donation)-Reference-Cited by-同舟云学术

Transient Palladadiphosphanylcarbenes: Singlet Carbenes with an “Inverse” Electronic Configuration (pπ2 instead of σ2) and Unusual Transannular Metal−Carbene Interactions (πC→Pd Donation and σPd→C Back-donation)

Published:2007-01-01 Issue:4 Volume:129 Page:978-985
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Vignolle Joan¹,Gornitzka Heinz¹,Maron Laurent¹,Schoeller Wolfgang W.¹,Bourissou Didier¹,Bertrand Guy¹

Affiliation:

1. Contribution from the Laboratoire Hétérochimie Fondamentale et Appliquée du CNRS (UMR 5069), Université Paul Sabatier, 118, route de Narbonne, F-31062 Toulouse Cedex 9, France, Laboratoire de Nanophysique, Magnétisme et Optoélectronique (LNMO), INSA, Université Paul Sabatier, 135, avenue de Rangueil, F-31077 Toulouse Cedex, France, Fakultät für Chemie der Universität, Postfach 10 01 31, D-33615 Bielefeld, Germany, and UCR−CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry,...

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja066738j

Reference56 articles.

1. Heterocyclic Carbenes

2. Looking for Stable Carbenes: The Difficulty in Starting Anew

3. Cyclopropenylidenes: From Interstellar Space to an Isolated Derivative in the Laboratory

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