The Prototype Ge−H Insertion Reaction of Germylene with Germane. Absolute Rate Constants, Temperature Dependence, RRKM Modeling and the Potential Energy Surface-Reference-Cited by-同舟云学术

The Prototype Ge−H Insertion Reaction of Germylene with Germane. Absolute Rate Constants, Temperature Dependence, RRKM Modeling and the Potential Energy Surface

Published:1998-11-20 Issue:48 Volume:120 Page:12657-12665
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Becerra Rosa¹,Boganov Sergei E.¹,Egorov Mikhail P.¹,Faustov Valery I.¹,Nefedov Oleg M.¹,Walsh Robin¹

Affiliation:

1. Contribution from the Instituto de Quimica-Fisica “Rocasolano”, C.S.I.C., C/Serrano 119, 28006 Madrid, Spain, the N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospekt 47, 117913 Moscow, Russian Federation, and the Department of Chemistry, University of Reading, Whiteknights, P.O. Box 224, Reading RG6 6AD, UK

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja983223m

Reference46 articles.

1. The photo-induced reaction of digermane with the Si(100)(2 × 1):D surface

2. Thermal decomposition of diethylgermane on Si(100)‐(2×1)

3. Kinetics and mechanism of the germane decomposition

4. Germanium atoms. Reactions with germane and silane

5. Room temperature observation of GeH2 and the first time-resolved study of some of its reactions

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