Structural studies on polynuclear osmium carbonyl hydrides. 6. (.mu.-H)Os3(CO)8[C(O-)C(CHMe-)CHCHCEt], a species with a trisubstituted .eta.5-cyclopentadienyl ring derived via extrusion of osmium from an osmiacyclohexadienone system
Author:
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic50183a038
Reference19 articles.
1. Structural studies on polynuclear osmium carbonyl hydrides. 1. Crystal structures of the isomorphous species undecacarbonyldihydrotriosmium and dodecacarbonyltriosmium. Role of an equatorial .mu.2-bridging hydride ligand in perturbing the arrangement of carbonyl ligands in a triangular cluster
2. Structural studies on polynuclear osmium carbonyl hydrides. 2. Direct location of the .mu.2-hydride ligand and characterization of the 1,3-dipolar :C-HCH2P+Me2Ph ligand in the .mu.-hydrido-decacarbonyl(dimethylphenylphosphine)-.mu.-vinyl-triosmium molecule
Cited by 33 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Reaction of [Os3(µ-H)2(CO)9(µ3-CNC5H4CHCH2)] with phenylacetylene. A novel type of alkylidyne–alkyne coupling in a triosmium alkylidyne cluster;J. Chem. Soc., Dalton Trans.;1995
2. Trinuclear Clusters of Ruthenium and Osmium: (iii) Clusters with Metal–Carbon Bonds to Heteroatom Ligands;Comprehensive Organometallic Chemistry II;1995
3. Stepwise C-H Cleavage of Two Methyl Groups of a Pentamethylcyclopentadienyl Ligand on a Tetraosmium Cluster;Organometallics;1994-12
4. Cluster chemistry. 79. Formation of unusual phosphine ligands by three-component condensation reactions on ruthenium cluster. X-ray structures of Ru4[.mu.4-.sigma.(O,P),.sigma.,.eta.2-C5H4(O)(PPh2)](.mu.-PPh2)(CO)11 and Ru4[.mu.4-.sigma.(O,P),.sigma.,.eta.2-C6H3(CO)(PPh2)](.mu.-PPh2)(CO)9(.eta.3-C4H7);Organometallics;1992-03
5. Synthesis of two novel pentanuclear rhodium clusters bearing the alkyl-like ligands CH2COOMe and CH2CN. X-ray structure of [PPh4]2[Rh5(.mu.-CO)6(CO)8(CH2CN)];Organometallics;1991-10
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