Factors Affecting Migration of Tertiary Alkyl Groups in Reactions of Alkylboronic Esters with Bromomethyllithium
Author:
Affiliation:
1. School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, U.K.
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo4000459
Reference40 articles.
1. Toward an understanding of the factors responsible for the 1,2-migration of alkyl groups in borate complexes
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3. Facile transfer of tertiary alkyl groups from boron to carbon in the base-induced reaction of .alpha.,.alpha.-dichloromethyl methyl ether with organoboranes containing tertiary alkyl groups. Novel route to highly hindered trialkylcarbinols involving exceptionally mild conditions
4. Organoboranes. 35. Reaction of alkylthioboronic esters with trichloromethyllithium: preparation of one-carbon-extended carboxylic acids and thioacetals from alkenes via hydroboration
5. Lithium tris(phenylthio)methane for the homologation of trialkylboranes: Convenient syntheses of ketones and t-carbinols
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