Ru(xantsil)(CO)(PCy3): Facile Generation of a Coordinatively Unsaturated Ruthenium(II) Complex Bearing 14 Valence Electrons [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]
Author:
Affiliation:
1. Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om049379e
Reference12 articles.
1. Is π-donation the only way? Unprecedented unsaturated Ru(II) species devoid of π-donor ligands
2. Extremely Facile Arene Exchange on a Ruthenium(II) Complex Having a Novel Bis(silyl) Chelate Ligand (9,9-Dimethylxanthene-4,5-diyl)bis(dimethylsilyl) (Xantsil)
3. Coordinatively Unsaturated Ru(II) Species Ru(xantsil)(CO): A New Active Catalyst for Oligomerization/Deoligomerization of HSiMe2SiMe3[xantsil=(9,9-Dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]. Isolation of a Stabilized Form of the Silyl(silylene) Intermediates
4. Synthesis, structure, and reactivity of hydridobis(silylene)ruthenium(IV)-xantsil complexes (xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)) — A stabilized form of key intermediates in the catalytic oligomerization–deoligomerization of hydrosilanes
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1. Synthesis of ruthenium–bis(silyl) chelate complexes without carbonyl ligands by reactions of a bis(allyl)ruthenium(II) complex with bis(hydrosilyl)xanthene and phosphines;Journal of Organometallic Chemistry;2020-07
2. Synthesis and Unique Catalytic Reactivity of Metal Complexes with Chelate-Type Silyl Ligands Connected by Xanthene;Journal of Synthetic Organic Chemistry, Japan;2018-12-01
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4. Directed ortho-C–H Silylation Coupled with trans-Selective Hydrogenation of Arylalkynes Catalyzed by Ruthenium Complexes of a Xanthene-Based Si,O,Si-Chelate Ligand, “Xantsil”;Organometallics;2016-04-15
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