Catalytic Enantioselective Diels−Alder Reaction via a Chiral Indium(III) Complex

Author:

Teo Yong-Chua1,Loh Teck-Peng1

Affiliation:

1. Division of Chemistry and Biological Chemistry, Nanyang Technological University, Singapore 637616, and Department of Chemistry, 3 Science Drive, National University of Singapore, Singapore 117543

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference6 articles.

1. Organic syntheses using indium-mediated and catalyzed reactions in aqueous media

2. For reviews, see: (a) Corey, E. J.Angew. Chem., Int. Ed.2002,41, 1650. (b) Evans, D. A.; Johnson, J. S. InComprehensive Asymmetric Catalysis; Jacobson, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer:  Berlin, 1999; Vol. 3, p 1177. (c) Diaz, L. C.J. Brz. Chem. Soc.1997,2, 289. (d) Corey, E. J.; Guzman-Perez, A.Angew. Chem., Int. Ed.1998,37, 488. (e) Ishihara, K.; Yamamoto, H.Eur. J. Org. Chem.1938,3, 527. (f) Narasaka, K.Stereocontrolled Org.Synth.1994, 17. For representative examples on catalytic enantioselective Diels−Alder reactions, see:  (g) Ryu, D. H.; Zhou, G.; Corey, E. J.J. Am. Chem. Soc.2004,126, 4800. (h) Sprott, K. T.; Corey, E. J.Org. Lett.2003,5, 2465. (i) Ryu, D. H.; Corey, E. J.J. Am. Chem. Soc.2003,125, 6388. (j) Nakano, H.; Suzuki, Y.; Kabuto, C.; Fujita, R.; Hongo, H.J. Org. Chem.2002,67, 5011. (k) Northrup, A. B.; MacMillan, D. W. C.J.Am. Chem. Soc.2002,124, 2458. (l) Corey, E. J.; Shibata, T.; Lee, T. W.J.Am. Chem. Soc.2002,124, 3808. (m) Ryu, D. H.; Lee, T. W.; Corey, E. J.J.Am. Chem. Soc.2002,124, 9992. (n) Breuning, M.; Corey, E. J.Org. Lett.2001,3, 1559.

3. Chiral Bis(oxazoline)copper(II) Complexes as Lewis Acid Catalysts for the Enantioselective Diels−Alder Reaction

4. Catalytic asymmetric allylation of aldehydes via a chiral indium(iii) complex

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