Electronic Structure, Porphyrin Core Distortion, and Fluxional Behavior of Bis-Ligated Low-Spin Iron(II) Porphyrinates
Author:
Affiliation:
1. Institut für Physik, Medizinische Universität zu Lübeck, 160 Ratzeburger Allee, 23538 Lübeck, Germany, and Department of Chemistry, University of Arizona, Tucson, Arizona 85721
Publisher
American Chemical Society (ACS)
Subject
Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jp963039s
Reference45 articles.
1. Hindered rotation of axially coordinated 2-methylimidazoles in tetramesitylporphyrinato-iron(III) complexes
2. Models of the cytochromes b. 8. Two-dimensional nuclear Overhauser and exchange spectroscopy studies of paramagnetic "cavity" type (tetraphenylporphinato)iron(III) complexes of planar ligands
3. 2D NMR Investigations of the Rotation of Axial Ligands in Six-Coordinate Low-Spin Iron(III) and Cobalt(III) Tetraphenylporphyrinates Having 2,6-Disubstituted Phenyl Rings: Quantitation of Rate Constants from 1H EXSY Cross-Peak Intensities
4. Investigations of Rotation of Axial Ligands in Six-Coordinate Low-Spin Iron(III) Tetraphenylporphyrinates: Measurement of Rate Constants from Saturation Transfer Experiments and Comparison to Molecular Mechanics Calculations
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