Characterization and Dynamics of [Pd(L−L)H(solv)]+, [Pd(L−L)(CH2CH3)]+, and [Pd(L−L)(C(O)Et)(THF)]+ (L−L = 1,2-(CH2PBut2)2C6H4): Key Intermediates in the Catalytic Methoxycarbonylation of Ethene to Methylpropanoate-Reference-Cited by-同舟云学术

Characterization and Dynamics of [Pd(L−L)H(solv)]+, [Pd(L−L)(CH2CH3)]+, and [Pd(L−L)(C(O)Et)(THF)]+ (L−L = 1,2-(CH2PBut2)2C6H4): Key Intermediates in the Catalytic Methoxycarbonylation of Ethene to Methylpropanoate

Published:2002-03-26 Issue:9 Volume:21 Page:1832-1840
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Clegg William¹,Eastham Graham R.¹,Elsegood Mark R. J.¹,Heaton Brian T.¹,Iggo Jonathan A.¹,Tooze Robert P.¹,Whyman Robin¹,Zacchini Stefano¹

Affiliation:

1. Chemistry Department, University of Newcastle, Newcastle-upon-Tyne, U.K. NE1 7RU, Ineos Acrylics, PO Box 90, Wilton, Middlesborough, Cleveland, U.K. TS90 8JE, and Chemistry Department, University of Liverpool, Liverpool, U.K. L69 7ZD

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om010938g

Reference24 articles.

1. Highly active and selective catalysts for the production of methyl propanoate via the methoxycarbonylation of ethene

2. Synthesis and spectroscopic characterisation of all the intermediates in the Pd-catalysed methoxycarbonylation of ethene

3. Synthesis of coordinatively unsaturated diphosphine nickel(II) and palladium(II)β-agostic ethyl cations: X-ray crystal structure of [Ni{But2P(CH2)2PBut2}(C2H5)][BF4]

4. Preparation and properties of ethylpalladium thiolate complexes. Reaction with organic halides leading to C–S bond formation; crystal structure of trans-[PdEt(Br)(PMe3)2]

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