Mechanism for the Formation of Substituted Manganese(V) Cyanidonitrido Complexes: Crystallographic and Kinetic Study of the Substitution Reactions of trans-[MnN(H2O)(CN)4]2− with Monodentate Pyridine and Bidentate Pyridine−Carboxylate Ligands

Author:

van der Westhuizen Hendrik J.1,Meijboom Reinout1,Schutte Marietjie2,Roodt Andreas2

Affiliation:

1. Department of Chemistry, University of Johannesburg, P.O. Box 524, Auckland Park, 2006, South Africa

2. Department of Chemistry, University of the Free State, P.O. Box 339, Bloemfontein, 9300, South Africa

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Reference54 articles.

1. Leipoldt, J. G., Basson, S. S., and Roodt, A.InAdvances in Inorganic Chemistry;Sykes, A. G., Ed; Academic Press: New York, 1993; Vol.40, p297.

2. Roodt, A., Abou-Hamdan, A., Engelbrecht, H. P., and Merbach, A. E.InAdvances in Inorganic Chemistry;Sykes, A. G., Ed; Academic Press: New York, 2000; Vol.49, p59.

3. Solid-state and theoretical structural study on trans-[ReO2(Eten)2]CF3SO3·LiCF3SO3 (Eten=N-ethyl ethylenediamine)

4. Solid State Study on Rhenium Dimethylphosphinoethane Complexes: X‐ray Crystal Structures of trans‐[ReO2(dmpe)2]PF6·2H2O, trans‐[ReO(OH)(dmpe)2](CF3SO3)2, trans‐[ReN(Cl)(dmpe)2]CF3SO3 and trans‐[ReCl2(dmpe)2]ReO4

5. Roodt, A., Engelbrecht, H. P., Botha, J. M., and Otto, S.InTechnetium, Rhenium and Other Metals in Chemistry and Nuclear Medicine;Nicolini, M.,Mazzi, U., Eds.; S G Editorial Publishers: Padova, Italy, 1999; Vol.5, p161.

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