Oxidation of a Monomethylpalladium(II) Complex with O2 in Water: Tuning Reaction Selectivity to Form Ethane, Methanol, or Methylhydroperoxide
Author:
Affiliation:
1. The Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, United States
Funder
Division of Chemistry
Basic Energy Sciences
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/jacs.5b12832
Reference36 articles.
1. Carbon-hydrogen bond activation by electrophilic transition-metal compounds. Palladium(II)-mediated oxidation of arenes and alkanes including methane
2. Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
3. Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization
4. Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions
5. Overcoming the “Oxidant Problem”: Strategies to Use O2 as the Oxidant in Organometallic C–H Oxidation Reactions Catalyzed by Pd (and Cu)
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