Synthesis of Hindered and Functionalized 1-CF3 Substituted Olefins via a Carbolithiation−Elimination−Metalation Cascade
Author:
Affiliation:
1. BIOCIS CNRS-URA 1843, Centre d'Etudes Pharmaceutiques, Rue J. B. Clément, Châtenay-Malabry, F-92296, France
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo961356p
Reference25 articles.
1. Wardell. J. L.Inorganic Reactions and methodsVCH: New York, 1988; Vol 11, p 129−142. Knochel P. InComprehensive Organic Synthesis; Trost, B., Fleming, I., Eds.; Pergamon: Oxford, 1991; Vol. 4, Chapter 44, p 865.
2. Synthesis and functionalisation of intermediates derived from allylmagnesiation of (E)-1-(trimethylsilyl)-but-1-en-3-ol
3. Asymmetric carbolithiation of cinnamyl derivatives in the presence of (-)-sparteine.
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