Synthesis and Reactivity of Conformationally Locked α-Aminoorganostannanes and α-Aminoorganolithiums. Discovery of a Surprising Configurational Requirement for Transmetalation-Reference-Cited by-同舟云学术

Synthesis and Reactivity of Conformationally Locked α-Aminoorganostannanes and α-Aminoorganolithiums. Discovery of a Surprising Configurational Requirement for Transmetalation

Published:2000-05-05 Issue:11 Volume:2 Page:1561-1564
ISSN:1523-7060
Container-title:Organic Letters
language:en
Short-container-title:Org. Lett.

Author:

Chambournier Gilles¹,Gawley Robert E.¹

Affiliation:

1. Department of Chemistry, University of Miami, P.O. Box 249118, Coral Gables, Florida 33124

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ol005770u

Reference18 articles.

1. Dipole-stabilized carbanions: novel and useful intermediates

2. 2-Lithio-N-methylpiperidine and 2-lithio-N-methylpyrrolidine: configurationally and chemically stable unchelated .alpha.-aminoorganolithiums

3. Alkylation of 2-lithio-N-methylpiperidines and -pyrrolidines: scope, limitations, and stereochemistry

4. Search for configurationally stable, aracemic α-amino organolithiums

5. A proposal for (slight) modification of the hughes-ingold mechanistic descriptors for substitution reactions

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