Oxidative Addition to a Monomeric Stannylene To Give Four-Coordinate Tin Compounds Containing the Bulky Bidentate Ligand C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C. Crystal Structures of CH2Me2Si(Me3Si)2CSnC(SiMe3)2SiMe2CH2, CH2Me2Si(Me3Si)2CSnMe(OCOCF3)C(SiMe3)2SiMe2CH2, and (CF3COO)2MeSnC(SiMe3)2SiMe2CH2CH2Me2Si- (Me3Si)2CSnMe(OCOCF3)2
Author:
Affiliation:
1. School of Chemistry, Physics and Environmental Science, University of Sussex, Brighton BN1 9QJ, U.K.
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om990779p
Reference22 articles.
1. Synthesis, structure and reactions of organometallic compounds of Groups 1–3 containing bulky silicon-substituted alkyl groups
2. Attachment of the Bulky Bidentate Ligand C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C to K, Zn, Sn, and Yb. Crystal Structures of LnMC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2CMLn (MLn = K(C6H6)2, K(THF)2, SnCl3, or SnMe2Cl) and CH2SiMe2C(SiMe3)2ZnC(SiMe3)2SiMe2CH2 (THF = Tetrahydrofuran)
3. Di[tris(trimethysilyl)methyl]-zinc and -cadmium
4. A Monomeric Solvent-Free Bent Lanthanide Dialkyl and a Lanthanide Analog of a Grignard Reagent. Crystal Structures of Yb{C(SiMe3)3}2 and [Yb{C(SiMe3)3}I.cntdot.OEt2]2
5. The first structurally characterised solvent-free ς-bonded diorganocalcium, Ca[C(SiMe3)3]2
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